Electrolytes in the VRB serve as energy storage medium, and are composed of vanadium ions of different valences in the supporting electrolytes. V (V) and V (IV) coexist in the positive electrolyte and V (III) and V (II) in the negative one. The electrolyte, a crucial component utilized in VRFB, has been a research hotspot due to its low-cost preparation technology and performance optimization methods. By dissolving V2O5 in aqueous HCl and H2SO4, subsequently adding glycerol as a reducing agent, we have demonstrated an inexpensive route for electrolyte synthesis to. Vanadium redox flow batteries (VRFBs) are promising candidates for large-scale energy storage, and the electrolyte plays a critical role in chemical–electrical energy conversion.